Great find!
I don't think it is the Militär-Sanitäts-Orden (I don't think this came as a pin-back award).
Perhaps it could be the Fürstlich Hohenzollernscher Bene Merenti?
Baden Golden Wedding Anniversary Commemorative Medal.
More info here: https://wawards.org/en/germany/german-empire/grand-duchy-of-baden/commemorative-medal-1906.html
Seems he only mounted his Prussian decorations.
The second medal is possibly the Red Eagle Order 4th Class with Swords (on same ribbon as the Iron Cross).
Just guessing:
1. Italian Order of SS. Maurice & Lazarus
2. Italian Order of the Crown
3. Hungarian Order of Merit
4. Yugoslav Order of St. Sava
5. Bulgarian Order of Military Merit
6. ???
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