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1. Order of the People's Republic of Bulgaria (Bulgaria, awarded to Dragoslav Marković)
2. Order of the Madar Horseman (Bulgaria, awarded to Dragoslav Marković)
3. Order of People's Freedom (Bulgaria, awarded to Koča Popović)
4. Commemorative Medal 90 Years of George Dimitrov's Birth (Bulgaria, awarded to Dragoslav Marković)
5. Banner of Labor (DDR, awarded to Dragoslav Marković)

Order of Suvorov 1st and 2nd class (USSR, awarded to Koča Popović)

As promised photos from exhibition "Decorations in the legacies of the Historical Archives of Belgrade" ("Одликовања из легата Историјског архива Београда").
Really amazing decorations, most of them I saw for the first time in person. Taking photos is allowed, staff is very pleasant, I was even offered magnifying glass to look at the orders more carefully. You also get a free leaflet and as I already mentioned complete illustrated catalog in PDF can be downloaded for free (Just in case someone missed it I posted it here: http://gmic.co.uk/topic/57613-decorations-from-the-collections-of-the-serbian-museums/?page=11#comment-626092 ).

1. Order of Hungarian Flag (Hungary, awarded to Koča Popović)
2. Order of Romanian Star (Romania, awarded to Vicko Krstulović)
3. Order of Tudor Vladimirescu (Romania, awarded to Dragoslav Marković)
4. Order of Partisan Star (Albania, awarded to Koča Popović)

Very nice! Document for 3rd class awarded to Aleksa Radulović (Алекса Радуловић) public attorney, signed by King Aleksandar.

Photos from awarding ceremonies.

Owain thank you very much for these information!
 

Thanks Chris.
I've done a little research and it turns out Egyptian orders were issued with buttonhole rosette (at least some of them). The main reason why I thought it could be Egyptian is because it belonged to Yugoslav diplomat who served there. Here's an example of 3rd class decoration with rosette (photo found on ebay).

I stumbled upon this buttonhole rosette and I was wondering could it be for Egyptian Order of Merit 1st class?

Medal for Contribution to the Defense System of the Republic of Serbia (photos found on ebay)

Medal for Zealous Military Service (10 years)

Found these online. 

Medal for Exceptional Achievements in Military Service (Officers)

 

Sometimes you can read comments that examples with such a huge numbers are from storage because there were around 120.000 of them awarded. That's not the case with this one because it came with a document, it was awarded in 1953. But we also know that decorations unfortunately weren't issued according to their number.

ZIN, so far the highest number I've seen!

Don't mention it Paul, all that I do is share images and material I find on Serbian websites 

I forgot to mention, complete catalog (in Serbian) is available for download on this page:
http://www.arhiv-beograda.org/index.php/rs/izlozba-odlikovanja

I will also upload it here just in case it one day disappears.
Odlikovanja (Istorijski arhiv Beograda).pdf

You're welcome. I've been trying to find someone I could borrow decent camera from for the exhibition.
Anyway once I make photos I'll post them here.

Filip Hristić (Филип Христић) representative of Serbia in Constantinople, Vienna and London from 1878 to 1883.
https://en.wikipedia.org/wiki/Filip_Hristić

Everything's kept in Historical Archives of Belgrade http://www.arhiv-beograda.org/index.php/en/
Photos found here: http://www.stalnapostavka.arhiv-beograda.org/index.php/en/chapters/legacies

By the way there's exhibition of decorations from legacies, it will be opened until the end of October http://www.arhiv-beograda.org/index.php/en/news/252-odlikovanja

Exhibition leaflet in PDF:  Exhibition leaflet.pdf

National Order of Merit 1st class (France)

Order of the Aztec Eagle 1st class (Mexico)

Order of the People's Republic of Bulgaria 1st Class

Order of Merit 2nd class (Congo)

Order of the Hero of Socialist Labour

Order of the Yugoslav Star 1st class

Order of the People's Hero (Soviet type)

Order of the Republic 1st class (Early type with 5 torches and I presume real stones)